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Retirement and forum shutdown (17 Jan 2022)

Hi,

John Howell who has managed the forum for years is getting on and wishes to retire from the role of managing it.
Over the years, he has managed the forum through good days and bad days and he has always been fair.
He has managed to bring his passion for fish keeping to the forum and keep it going for so long.

I wish to thank John for his hard work in keeping the forum going.

With John wishing to "retire" from the role of managing the forum and the forum receiving very little traffic, I think we must agree that forum has come to a natural conclusion and it's time to put it to rest.

I am proposing that the forum be made read-only from March 2022 onwards and that no new users or content be created. The website is still registered for several more years, so the content will still be accessible but no new topics or replies will be allowed.

If there is interest from the ITFS or other fish keeping clubs, we may redirect traffic to them or to a Facebook group but will not actively manage it.

I'd like to thank everyone over the years who helped with forum, posted a reply, started a new topic, ask a question and helped a newbie in fish keeping. And thank you to the sponsors who helped us along the away. Hopefully it made the hobby stronger.

I'd especially like to thank John Howell and Valerie Rousseau for all of their contributions, without them the forum would have never been has successful.

Thank you
Darragh Sherwin

prime and the such

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01 May 2011 17:45 #1 by dar (darren curry)
i use prime water conditioner and it states it removes ammonia. i have no idea how these ammonia removing products work, but out of curiosity wat does the bacteria eat if it removes ammonia or does the ingredient just remove existing ammonia and is then non active? could this somehow restart the cycle if you were doing a daily 10% water change?

Check out the angling section, it is fantastic

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01 May 2011 20:43 #2 by igmillichip (ian millichip)
There are 2 very good questions there, Dar.

I don't use Prime.
I'm more of a Tetra Aqua Safe person (tradition and all that), but I also have AmQuel and zeolites for removing ammonia from the tank if there is ever a need for such action.

I like to know exactly what is in the chemicals I add.
Tetra AquaSafe contains sodium hydroxymethanesulfinate as a means to remove ammonia from the 'breakdown' of chloramines. It is not really intended for use in removing ammonia within the tank.

In AmQuel, there is Sodium hydroxymethanesulfonate. That is intended to remove ammonia from a fish tank.

The way that AmQuel works is by 'binding' up the ammonia to the above chemical (ie effectively it keeps the hydrogen attached to an ammonium group) such that there is something (aminomethanesulfonate) that is very very much less toxic to fish. Methanal (formaldehyde) looks as though it is released in this reaction...but it should be nothing to worry about.

As for Prime??? I don't use it, so have never really looked much closer at it.
But there are words that it contains a complex mix of hydrosulphites and bisulphites.

Now going by its action on ammonia and nitrites and nitrates and some of the known chemicals in it, I'm guessing that it produces a cyclic imine (a Schiffs base) to 'bind up' the ammonia.


Next point raised.....what will the nitrosofying bacteria use as a substrate if ammonia is bound up?

As said, I don't use Prime (that's the 3rd time I've said that :) ), but it may work like that of AmQuel and AquaSafe wrt feeding nitrosofying bacteria.
The ammonium moiety on the complexed compound can be utilised by nitrosofying bacteria....hence ammonia would be available.

If you used zeolite resins, then that would not be the case.

But is everything hunky dory? nope. !!!!
You should not really measure ammonia after addition of AmQuel or Prime or any other reagent that complexes the ammonia/ammonium moiety......well, you could do the ammonia test, but the results may not be accurate unless somehow you have accounted for the action of the ammonia-removing reagent:
at the pH of most common ammonia test kits, the ammonia would be released and measured by the kit as a false positive.

Remember, you are not interested in how much ammonia would be in the tank if you didn't remove the ammonia....you want to know how much free unionised ammonia (the highly toxic stuff) is in the tank.

Hope I didn't go too scientific (although you did ask for a chemical reaction), but hope that may go to help answer the question.
If the makers of Prime told us exactly what was in it, then I could be of more help.

ian

Irish Tropical Fish Society (ITFS) Member.

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01 May 2011 23:19 #3 by DJK (David Kinsella)
Prime has to be the best value for money as regards mils to litres. I've used it before without any issues whatsoever. This topic has come up before with Platy 252 recommening it highly, so that's enough for me.

Dave

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